Wednesday, January 16, 2019
Chem
Organic Chemistry I Spring 2013 Practice test 1. lean the following compounds a. 5-tert-butyl-7-isopropyl-6-sec-butyl-undecane b. cis-2-(5,6-dimethylheptyl)-6-(3-methylpentyl)piperidine c. trans -2-nonyl-3-octyl-tetrahydrofuran d. trans-1,6-dimethylbicyclo4. 3. 0nonane e. cis-6,8-ditert-butylspiro3. 5nonane f. 1,6-dimethylcyclohexene g. (Z)-3-bromo-4-fluoro-5-methyl-oct-4-ene h. (E)-8-(1-chloroethyl)nonadec-8-ene 2. Draw the grammatical constructions of the following compounds a b e c f d g h 3.Draw the structure of the following compounds in Newman projections and in chair conformations a b c d e 4. Draw the around stable isomer of 1-tert-butyl-3-methylcyclohexane. a. Which atoms/groups are i. inelegant to axial hydrogen on C2 A t-butyl, C6, methyl, C4 ii. anti to equatorial substituent on C3 A C5, C1 b. What is the descent between i. tert-butyl group and equatorial hydrogen on C2 A gauche ii. equatorial hydrogen on C4 and C6 A anti 5. Draw all isomers of 4-tert-butyl-2-ethyl -1-methylcyclohexane (ignore mirror images) in their most stable conformations.Arrange the structures from the least stable to the most stable. 6. Cyclohexylmethanol and 1-methylcyclohexanol are converted to their corresponding bromides. Write a suitable apparatus for each reaction, and assign each the appropriate symbol (SN1 or SN2). OH O H H Br H + Br SN2 Br O H H Br + H2O OH O H Br O + H2O + Br SN1 Br Br 7. Give the structure of the principal organic product formed by photochemical bromination of methylcyclopropane, find the mechanism of the reaction. Br2, h? h? Br Br H . .Br Br Br Br 2Br . . + HBr Br + . Br
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